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|Section2= |Section3= }} Iodine heptafluoride, also known as iodine(VII) fluoride or iodine fluoride, is an interhalogen compound with the chemical formula IF7.〔Macintyre, J. E. (Ed.). (1992). ''Dictionary of Inorganic Compounds'' (Vol. 3). London: Chapman & Hall.〕〔O'Neil, Maryadele J. (Ed.). (2001). ''The Merck Index'' (13th ed.). Whitehouse Station, NJ: Merck.〕 It has an unusual pentagonal bipyramidal structure, as predicted by VSEPR theory. The molecule can undergo a pseudorotational rearrangement called the Bartell mechanism, which is like the Berry mechanism but for a heptacoordinated system. It forms colourless crystals, which melt at 4.5 °C: the liquid range is extremely narrow, with the boiling point at 4.77 °C. The dense vapor has a mouldy, acrid odour. The molecule has D5h symmetry. ==Preparation== IF7 is prepared by passing F2 through liquid IF5 at 90 °C, then heating the vapours to 270 °C. Alternatively, this compound can be prepared from fluorine and dried palladium or potassium iodide to minimize the formation of IOF5, an impurity arising by hydrolysis. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Iodine heptafluoride」の詳細全文を読む スポンサード リンク
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